Crown Ethers And Analogous Compounds Michio Hiraoka

ISBN: 9780444881915

Published: January 1st 1992

Hardcover

485 pages


Description

Crown Ethers And Analogous Compounds  by  Michio Hiraoka

Crown Ethers And Analogous Compounds by Michio Hiraoka
January 1st 1992 | Hardcover | PDF, EPUB, FB2, DjVu, AUDIO, mp3, RTF | 485 pages | ISBN: 9780444881915 | 10.50 Mb

Since the discovery of crown ethers by Pedersen in 1967, several thousands of crown ethers and analogous compounds have been synthesized. Their specific characteristics have been investigated and a variety of applications developed. TheseMoreSince the discovery of crown ethers by Pedersen in 1967, several thousands of crown ethers and analogous compounds have been synthesized.

Their specific characteristics have been investigated and a variety of applications developed. These developments have led to new fields of chemistry called host-guest chemistry and supramolecular chemistry. This book presents the state-of-the-art of the chemistry of crown ethers and analogous compounds.

Chapter 2 reviews advances in synthetic procedures for crown ethers and analogous compounds including azacrown ethers, thiacrown ethers, functionalized crown ethers, cryptands and others. The focus of chapter 3 is on the concept and synthetic strategies for the molecular design of new crown compounds. Chapters 4-7 are concerned with noteworthy topics in the applications of crown compounds. Chapter 4 deals with the application to ion-selective electrodes and liquid chromatography, both of which are the most important targets in the analytical application of crown compounds.

One major application of crown ethers is the design and syntheses of artificial molecules which can catalyze a useful synthetic reaction in an enzyme-mimetic reaction manner, through novel non-covalent complexes. The strategies for enzymatic modelling with crown ethers are covered in chapter 5, while chapter 6 presents the principle of amine-selective colour complexation and its application.

In chapter 7 switched-on crown ethers that can respond to environmental stimuli are reviewed. pharmaceutical chemistry and industrial chemistry will find this book a helpful summary and a stimulating contribution to research in this specialized field of crown compounds.



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